Measurement of absorption cross sections and spectroscopic molecular parameters

O2 and its collisonal induced absorption

High resolution spectra of O2

* Herzberg bands

o2_herzb.txt - Assignments and intensities in the 41261-34000 cm-1 region
o2_param.txt - Molecular parameters and the transition moments
non_att.txt - Lines unidentified

Reference 1 : A. Jenouvrier, M.-F. Mérienne, B. Coquart, M. Carleer, S. Fally, A. C. Vandaele, C. Hermans, and R. Colin, Fourier transform spectroscopy in the O2 Herzberg bands: I- Rotational analysis, J. Mol. Spectrosc., 198, 136-162 (1999)
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Reference 2 : M.-F. Mérienne, A. Jenouvrier, B. Coquart, M. Carleer, S. Fally, R. Colin, A.C. Vandaele, C. Hermans, Fourier transform spectroscopy of the O2 Herzberg bands. II. Band oscillator strengths and transition moments, J. Mol. Spectrosc., 202, 171-193 (2000)
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Reference 3 : M.-F. Mérienne, A. Jenouvrier, B. Coquart, M. Carleer, S. Fally, R. Colin, A.C. Vandaele and C. Hermans, Improved Data Set for the Herzberg Band Systems of O2, J. Mol. Spectrosc., 207, 120 (2001)
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Collision induced absorption in the UV (Wulf bands)

Temperature

287- 289 K
Pressures see data file
Spectral Interval
34000-41500 cm-1 (330-240 nm)
Resolution 2 cm-1

further information

C. Hermans of the BISA group

Reference : S. Fally , A. C. Vandaele , M. Carleer, C. Hermans, A. Jenouvrier, M.-F. Mérienne, B. Coquart and R. Colin, Fourier Transform Spectroscopy of the 02 Herzberg bands. III. Absorption cross-sections of the collision-induced bands and of the Herzberg continuum, J. Mol. Spectrosc., 204, 10-20 (2000)
Download article (.pdf, 196 KB)

Collision induced in the 30000-15000 cm-1 wavenumber region

Temperature
room temperature
Spectral Interval
15000-30000 cm-1 (666-333 nm)
Resolution

2 cm-1

further information C. Hermans of the BISA group

Pressures

O4 absorption cross-sections
Wave number range: 15000-29800 cm-1
Resolution: spectra recorded at a resolution of 2 cm-1, but filtered afterwards ; (Cutoff freq. of the filter: 0.015 /Nyq.)
Wave number units:cm-1 (in air)
Cross-sections units:cm-5/molec-2
Room temperature
These cross-sections are obtained from spectra recorded at different pressures (300-700 torr).


 

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